| Time | Status | Match | FT | H1 | Stats |
| 01/10/2021 20:00 |
(FT) | Athletic Bilbao[10] Alaves[19] |
1 0 |
1 0 |
MF | ME |
| 02/10/2021 13:00 |
(FT) | Osasuna[9] Rayo Vallecano[5] |
1 0 |
0 0 |
MF | ME |
| 02/10/2021 15:15 |
(FT) | Mallorca[12] Levante[17] |
1 0 |
0 0 |
MF | ME |
| 02/10/2021 17:30 |
(FT) | Cadiz[15] Valencia[8] |
0 0 |
0 0 |
MF | ME |
| 02/10/2021 20:00 |
(FT) | Atletico Madrid[4] Barcelona[6] |
2 0 |
2 0 |
MF | ME |
| 03/10/2021 13:00 |
(FT) | Elche[16] Celta Vigo[13] |
1 0 |
0 0 |
MF | ME |
| 03/10/2021 15:15 |
(FT) | Espanyol[14] Real Madrid[1] |
2 1 |
1 0 |
MF | ME |
| 03/10/2021 17:30 |
(FT) | Getafe[20] Real Sociedad[2] |
1 1 |
1 0 |
MF | ME |
| 03/10/2021 17:30 |
(FT) | Villarreal[11] Real Betis[7] |
2 0 |
1 0 |
MF | ME |
| 03/10/2021 20:00 |
(FT) | Granada[18] Sevilla[3] |
1 0 |
1 0 |
MF | ME |