| Time | Status | Match | FT | H1 | Stats |
| 27/08/2021 19:00 |
(FT) | Mallorca[5] Espanyol[14] |
1 0 |
1 0 |
MF | ME |
| 27/08/2021 21:15 |
(FT) | Valencia[4] Alaves[19] |
3 0 |
2 0 |
MF | ME |
| 28/08/2021 16:00 |
(FT) | Celta Vigo[16] Athletic Bilbao[11] |
0 1 |
0 1 |
MF | ME |
| 28/08/2021 18:30 |
(FT) | Elche[17] Sevilla[1] |
1 1 |
1 1 |
MF | ME |
| 28/08/2021 18:30 |
(FT) | Real Sociedad[7] Levante[8] |
1 0 |
1 0 |
MF | ME |
| 28/08/2021 21:00 |
(FT) | Real Betis[9] Real Madrid[3] |
0 1 |
0 0 |
MF | ME |
| 29/08/2021 16:00 |
(FT) | Barcelona[4] Getafe[18] |
2 1 |
2 1 |
MF | ME |
| 29/08/2021 18:30 |
(FT) | Cadiz[10] Osasuna[14] |
2 3 |
1 0 |
MF | ME |
| 29/08/2021 18:30 |
(FT) | Rayo Vallecano[20] Granada[12] |
4 0 |
3 0 |
MF | ME |
| 29/08/2021 21:00 |
(FT) | Atletico Madrid[2] Villarreal[13] |
2 2 |
0 0 |
MF | ME |