| Time | Status | Match | FT | H1 | Stats |
| 13/08/2021 20:00 |
(FT) | Valencia[13] Getafe[15] |
1 0 |
1 0 |
MF | ME |
| 14/08/2021 18:30 |
(FT) | Cadiz[12] Levante[14] |
1 1 |
0 1 |
MF | ME |
| 14/08/2021 18:30 |
(FT) | Mallorca[SPA D2-2] Real Betis[6] |
1 1 |
1 0 |
MF | ME |
| 14/08/2021 21:00 |
(FT) | Osasuna[11] Espanyol[SPA D2-1] |
0 0 |
0 0 |
MF | ME |
| 14/08/2021 21:00 |
(FT) | Alaves[16] Real Madrid[2] |
1 4 |
0 0 |
MF | ME |
| 15/08/2021 16:30 |
(FT) | Celta Vigo[8] Atletico Madrid[1] |
1 2 |
0 1 |
MF | ME |
| 15/08/2021 19:00 |
(FT) | Barcelona[3] Real Sociedad[5] |
4 2 |
2 0 |
MF | ME |
| 15/08/2021 21:15 |
(FT) | Sevilla[4] Rayo Vallecano[SPA D2-6] |
3 0 |
1 0 |
MF | ME |
| 16/08/2021 19:00 |
(FT) | Villarreal[7] Granada[9] |
0 0 |
0 0 |
MF | ME |
| 16/08/2021 21:00 |
(FT) | Elche[17] Athletic Bilbao[10] |
0 0 |
0 0 |
MF | ME |