| Time | Status | Match | FT | H1 | Stats |
| 07/10/2022 20:00 |
(FT) | Osasuna[6] Valencia[9] |
1 2 |
0 1 |
MF | ME |
| 08/10/2022 13:00 |
(FT) | Almeria[18] Rayo Vallecano[10] |
3 1 |
3 0 |
MF | ME |
| 08/10/2022 15:15 |
(FT) | Atletico Madrid[5] Girona[13] |
2 1 |
1 0 |
MF | ME |
| 08/10/2022 17:30 |
(FT) | Sevilla[17] Athletic Bilbao[3] |
1 1 |
1 0 |
MF | ME |
| 08/10/2022 20:00 |
(FT) | Getafe[14] Real Madrid[2] |
0 1 |
0 1 |
MF | ME |
| 09/10/2022 13:00 |
(FT) | Valladolid[15] Real Betis[4] |
0 0 |
0 0 |
MF | ME |
| 09/10/2022 15:15 |
(FT) | Cadiz[19] Espanyol[16] |
2 2 |
1 0 |
MF | ME |
| 09/10/2022 17:30 |
(FT) | Real Sociedad[7] Villarreal[8] |
1 0 |
1 0 |
MF | ME |
| 09/10/2022 20:00 |
(FT) | Barcelona[1] Celta Vigo[11] |
1 0 |
1 0 |
MF | ME |
| 10/10/2022 20:00 |
(FT) | Elche[20] Mallorca[12] |
1 1 |
1 0 |
MF | ME |