| Time | Status | Match | FT | H1 | Stats |
| 19/08/2022 19:00 |
(FT) | Espanyol[9] Rayo Vallecano[13] |
0 2 |
0 1 |
MF | ME |
| 19/08/2022 21:00 |
(FT) | Sevilla[14] Valladolid[16] |
1 1 |
0 0 |
MF | ME |
| 20/08/2022 16:30 |
(FT) | Osasuna[3] Cadiz[19] |
2 0 |
1 0 |
MF | ME |
| 20/08/2022 18:30 |
(FT) | Mallorca[10] Real Betis[4] |
1 2 |
0 1 |
MF | ME |
| 20/08/2022 21:00 |
(FT) | Celta Vigo[8] Real Madrid[1] |
1 4 |
1 2 |
MF | ME |
| 21/08/2022 16:30 |
(FT) | Athletic Bilbao[11] Valencia[2] |
1 0 |
1 0 |
MF | ME |
| 21/08/2022 18:30 |
(FT) | Atletico Madrid[6] Villarreal[5] |
0 2 |
0 0 |
MF | ME |
| 21/08/2022 21:00 |
(FT) | Real Sociedad[7] Barcelona[12] |
1 4 |
1 1 |
MF | ME |
| 22/08/2022 19:00 |
(FT) | Elche[17] Almeria[18] |
1 1 |
1 1 |
MF | ME |
| 22/08/2022 21:00 |
(FT) | Girona[20] Getafe[15] |
3 1 |
1 0 |
MF | ME |