| Time | Status | Match | FT | H1 | Stats |
| 02/09/2022 20:00 |
(FT) | Celta Vigo[12] Cadiz[20] |
3 0 |
0 0 |
MF | ME |
| 03/09/2022 13:00 |
(FT) | Mallorca[9] Girona[13] |
1 1 |
0 0 |
MF | ME |
| 03/09/2022 15:15 |
(FT) | Real Madrid[1] Real Betis[2] |
2 1 |
1 1 |
MF | ME |
| 03/09/2022 17:30 |
(FT) | Real Sociedad[8] Atletico Madrid[6] |
1 1 |
0 1 |
MF | ME |
| 03/09/2022 20:00 |
(FT) | Sevilla[15] Barcelona[3] |
0 3 |
0 2 |
MF | ME |
| 04/09/2022 13:00 |
(FT) | Osasuna[7] Rayo Vallecano[11] |
2 1 |
0 0 |
MF | ME |
| 04/09/2022 15:15 |
(FT) | Athletic Bilbao[4] Espanyol[16] |
0 1 |
0 0 |
MF | ME |
| 04/09/2022 17:30 |
(FT) | Villarreal[5] Elche[17] |
4 0 |
2 0 |
MF | ME |
| 04/09/2022 20:00 |
(FT) | Valencia[14] Getafe[18] |
5 1 |
3 0 |
MF | ME |
| 05/09/2022 20:00 |
(FT) | Valladolid[19] Almeria[10] |
1 0 |
0 0 |
MF | ME |