| Time | Status | Match | FT | H1 | Stats |
| 27/09/2013 20:00 |
(FT) | Valladolid[13] Malaga[10] |
2 2 |
0 1 |
MF | ME |
| 28/09/2013 15:00 |
(FT) | Valencia[9] Rayo Vallecano[19] |
1 0 |
1 0 |
MF | ME |
| 28/09/2013 16:59 |
(FT) | Almeria[16] Barcelona[1] |
0 2 |
0 1 |
MF | ME |
| 28/09/2013 19:00 |
(FT) | Real Sociedad[7] Sevilla[20] |
1 1 |
0 1 |
MF | ME |
| 28/09/2013 21:00 |
(FT) | Real Madrid[3] Atletico Madrid[2] |
0 1 |
0 1 |
MF | ME |
| 29/09/2013 11:00 |
(FT) | Osasuna[18] Levante[10] |
0 1 |
0 0 |
MF | ME |
| 29/09/2013 16:00 |
(FT) | Celta Vigo[8] Elche[17] |
0 1 |
0 0 |
MF | ME |
| 29/09/2013 18:00 |
(FT) | Espanyol[5] Getafe[15] |
0 2 |
0 0 |
MF | ME |
| 29/09/2013 20:00 |
(FT) | Real Betis[12] Villarreal[4] |
1 0 |
1 0 |
MF | ME |
| 30/09/2013 21:00 |
(FT) | Granada[13] Athletic Bilbao[6] |
2 0 |
0 0 |
MF | ME |