| Time | Status | Match | FT | H1 | Stats |
| 24/09/2013 19:00 |
(FT) | Barcelona[1] Real Sociedad[7] |
4 1 |
3 0 |
MF | ME |
| 24/09/2013 19:00 |
(FT) | Levante[9] Valladolid[13] |
1 1 |
1 1 |
MF | ME |
| 24/09/2013 21:00 |
(FT) | Malaga[10] Almeria[18] |
2 0 |
0 0 |
MF | ME |
| 24/09/2013 21:00 |
(FT) | Atletico Madrid[2] Osasuna[20] |
2 1 |
2 1 |
MF | ME |
| 25/09/2013 19:00 |
(FT) | Granada[12] Valencia[16] |
0 1 |
0 0 |
MF | ME |
| 25/09/2013 19:00 |
(FT) | Sevilla[19] Rayo Vallecano[17] |
4 1 |
1 0 |
MF | ME |
| 25/09/2013 21:00 |
(FT) | Elche[15] Real Madrid[4] |
1 2 |
0 0 |
MF | ME |
| 26/09/2013 19:00 |
(FT) | Athletic Bilbao[5] Real Betis[11] |
2 1 |
0 0 |
MF | ME |
| 26/09/2013 21:00 |
(FT) | Getafe[14] Celta Vigo[8] |
2 0 |
1 0 |
MF | ME |
| 26/09/2013 21:00 |
(FT) | Villarreal[3] Espanyol[6] |
2 1 |
1 0 |
MF | ME |