| Time | Status | Match | FT | H1 | Stats |
| 07/02/2014 20:00 |
(FT) | Espanyol[10] Granada[14] |
1 0 |
0 0 |
MF | ME |
| 08/02/2014 15:00 |
(FT) | Valencia[8] Real Betis[20] |
5 0 |
2 0 |
MF | ME |
| 08/02/2014 17:00 |
(FT) | Rayo Vallecano[19] Malaga[13] |
4 1 |
3 0 |
MF | ME |
| 08/02/2014 19:00 |
(FT) | Real Madrid[3] Villarreal[5] |
4 2 |
2 1 |
MF | ME |
| 08/02/2014 21:00 |
(FT) | Almeria[17] Atletico Madrid[1] |
2 0 |
0 0 |
MF | ME |
| 09/02/2014 11:00 |
(FT) | Osasuna[16] Getafe[12] |
2 0 |
1 0 |
MF | ME |
| 09/02/2014 15:59 |
(FT) | Valladolid[18] Elche[15] |
2 2 |
0 1 |
MF | ME |
| 09/02/2014 18:00 |
(FT) | Real Sociedad[6] Levante[9] |
0 0 |
0 0 |
MF | ME |
| 09/02/2014 20:00 |
(FT) | Sevilla[7] Barcelona[2] |
1 4 |
1 2 |
MF | ME |
| 10/02/2014 21:00 |
(FT) | Celta Vigo[11] Athletic Bilbao[4] |
0 0 |
0 0 |
MF | ME |