| Time | Status | Match | FT | H1 | Stats |
| 21/10/2006 19:00 |
(FT) | Villarreal Levante |
1 1 |
0 0 |
MF | ME |
| 21/10/2006 19:00 |
(FT) | Zaragoza Real Betis |
2 1 |
2 0 |
MF | ME |
| 21/10/2006 21:00 |
(FT) | Deportivo La Coruna Atletico Madrid |
1 0 |
0 0 |
MF | ME |
| 22/10/2006 16:00 |
(FT) | Athletic Bilbao Celta Vigo |
0 1 |
0 1 |
MF | ME |
| 22/10/2006 16:00 |
(FT) | Espanyol Racing de Santander |
2 2 |
1 1 |
MF | ME |
| 22/10/2006 16:00 |
(FT) | Mallorca Real Sociedad |
0 0 |
0 0 |
MF | ME |
| 22/10/2006 16:00 |
(FT) | Recreativo Huelva Getafe |
1 2 |
0 1 |
MF | ME |
| 22/10/2006 16:00 |
(FT) | Sevilla Gimnastic Tarragona |
2 1 |
2 0 |
MF | ME |
| 22/10/2006 16:00 |
(FT) | Valencia Osasuna |
1 0 |
1 0 |
MF | ME |
| 22/10/2006 20:00 |
(FT) | Real Madrid Barcelona |
2 0 |
1 0 |
MF | ME |