| Minute | Score | Villarreal | Valladolid | |
| 35' | 0 - 0 | Mario Gaspar |
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| 36' | 0 - 0 | Cop D. |
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| 45' | 0 - 0 | Bacca C. |
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| 46' | 0 - 0 | Layun M. (Mario Gaspar) |
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| 53' | 0 - 1 |  Suarez L. |
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| 60' | 0 - 1 | Cazorla S. |
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| 66' | 0 - 1 | Ekambi K. (Cazorla S.) |
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| 70' | 0 - 1 | Tuhami A. M. (Suarez L.) |
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| 77' | 0 - 1 | Alfonso (Costa J.) |
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| 82' | 0 - 1 | Kiko |
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| 83' | 0 - 1 | Moreno G. (Penalty missed) |
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| 85' | 0 - 1 | Lopez I. (Toni) |
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| 85' | 0 - 1 | Nacho |
