| Time | Status | Match | FT | H1 | Stats |
| 18/10/2022 18:00 |
(FT) | Sevilla[18] Valencia[7] |
1 1 |
0 1 |
MF | ME |
| 18/10/2022 19:00 |
(FT) | Getafe[14] Athletic Bilbao[3] |
2 2 |
1 1 |
MF | ME |
| 18/10/2022 20:00 |
(FT) | Atletico Madrid[4] Rayo Vallecano[10] |
1 1 |
1 0 |
MF | ME |
| 19/10/2022 18:00 |
(FT) | Cadiz[19] Real Betis[5] |
0 0 |
0 0 |
MF | ME |
| 19/10/2022 18:00 |
(FT) | Valladolid[15] Celta Vigo[11] |
4 1 |
1 1 |
MF | ME |
| 19/10/2022 19:15 |
(FT) | Real Sociedad[6] Mallorca[12] |
1 0 |
1 0 |
MF | ME |
| 19/10/2022 20:00 |
(FT) | Elche[20] Real Madrid[2] |
0 3 |
0 1 |
MF | ME |
| 20/10/2022 18:00 |
(FT) | Almeria[18] Girona[15] |
3 2 |
3 0 |
MF | ME |
| 20/10/2022 19:00 |
(FT) | Osasuna[8] Espanyol[13] |
1 0 |
0 0 |
MF | ME |
| 20/10/2022 20:00 |
(FT) | Barcelona[2] Villarreal[9] |
3 0 |
3 0 |
MF | ME |